Oxidation State Calculator

Determine the oxidation state of elements in standard molecular formulas and polyatomic ions.

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Calculation Parameters

Specify your chemical inputs.

Calculated Result

Oxidation States C: +4, O: -2
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Expert Tip

Double check molecular weights and balance equations to ensure stoichiometric ratios are correct.

How this Calculator Works

This calculator assigns oxidation numbers to each element in a molecule or polyatomic ion based on hierarchical IUPAC electronegativity rules. Enter the formula below:

  • Chemical Formula: A compound formula like CO2, H2O, or KMnO4 (Default: CO2)

The results are computed instantly and updated in the results panel on the right.

Formula & Methodology

Sum of Oxidation States = Net Charge of Compound

Where:

  • Oxidation Number: The theoretical charge of an atom if all bonds were ionic.
  • Hierarchical Rules: Elements = 0; Group 1 = +1; Group 2 = +2; F = -1; H = +1 (with non-metals); O = -2.

Step-by-Step Calculation Example

To calculate the oxidation states of carbon and oxygen in Carbon Dioxide ($CO_2$) manually, follow these steps:

  1. Identify the input parameters. For example:
    • Formula = CO2
    • Net Charge = 0
    • Oxygen Rule = -2
  2. Apply the formula:
    Total charge = C_state + 2 * O_state = 0 x + 2 * (-2) = 0 x - 4 = 0 => x = +4 (Oxidation state of Carbon)
  3. Verify the calculated value which is updated instantly in the results panel on the right.

Frequently Asked Questions

What is an oxidation state? โ–ผ

An oxidation state (or number) represents the degree of oxidation of an atom in a chemical compound.

What is the oxidation state of elemental forms? โ–ผ

Free elements in their uncombined state always have an oxidation number of zero (e.g. O2, Fe, H2 = 0).

What is the typical oxidation state of Oxygen in compounds? โ–ผ

Oxygen is usually -2 in compounds, except in peroxides (-1) or bonded to Fluorine (+2).

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